[15][16][17], Fused silver nitrate, shaped into sticks, was traditionally called "lunar caustic". May be harmful if swallowed. When Silver (Ag) reacts with Nitric Acid (HNO3), the chemical reaction results in the formation of Silver Nitrate. Then silver nitrate solution is added. The primary halide may take considerably longer to produce a precipitate. Precipitates and solutions of silver precipitates, Sodium carbonate Physical Properties. In order for a halide ion to be produced, the carbon-halogen bond has to be broken. The resulting adduct can be decomposed with ammonia to release the free alkene. We all see different ceramic pottery in different colors. How is silver nitrate used in different industries? Legal. Such prints are left when sweat or natural body oils make contact with other surfaces. In this case, various halogenoalkanes are treated with a solution of silver nitrate in a mixture of ethanol and water. 3. Each Ag+ center is bonded to six oxygen centers of both uni- and bidentate nitrate ligands. of NH4SCN solution consumed as Volume IV. Generally, fingerprints are found in crime scenes. Silver Nitrate is used to add such colors in the ceramic works. As long as you are doing everything under controlled conditions (same amounts of everything, same temperature and so on), the time taken gives a good guide to the reactivity of the halogenoalkanes - the quicker the precipitate appears, the more reactive the halogenoalkane. Silver nitrate is an inorganic compound with chemical formula AgNO3. Molecular weight calculation: 107.8682 + 14.0067 + 15.9994*3. The color of precipitate varies with the halide: white (silver chloride), pale yellow/cream (silver bromide), yellow (silver iodide). Silver nitrate may intensify fire,Causes severe skin burns and eye damage and very toxic to aquatic life. This step avoids confusion of silver sulfide or silver carbonate precipitates with that of silver halides. For example, for the deprotection and oxidation reactions. AgNO3 . Mirrors reflect whatever is in front of it. Silver nitrate is used to cauterize and remove such moles. Vedantu LIVE Online Master Classes is an incredibly personalized tutoring platform for you, while you are staying at your home. Using the chemical formula of the compound and the periodic table of elements, we can add up the atomic weights and calculate molecular weight of the substance. 4zDu!r{QuS}~hK|g pSdwe[-32e]6}-o=tYu~H>$QT7C;x-,("soO|-p/?WEx>9/pptJOR8_{khQas|}p}A;^VEAc{;fL%1EbB__&,.vMC0(Bm6)8x(Em.:)5qoL? [CDATA[ acid is added to aqueous silver nitrate solution or silver chloride precipitate, Some of these uses of AgNO3 are listed below. Dry 17.5 g of silver nitrate (AgNO3) at 105C for 1 h. Cool in a desiccator. It is far less sensitive to light than the halides. A primary bromo compound takes longer to give a precipitate. | Silver Nitrate + Sodium Chloride Reaction. physics. Target Organs: Eyes, skin, mucous membranes. Chemical Compounds are of two types. The reaction between HCl and AgNO3 is a double displacement reaction as two species are interchanged to give products. Hence, one of the uses of Silver Nitrate is in the preparation of other Silver compounds. It consists of an ionic bond between the silver cation (Ag+) and the nitrate anion (NO3). The nitrate can be easily replaced by other ligands, rendering AgNO3 versatile. National Institutes of Health. hiring for, Apply now to join the team of passionate Select the correct answer and click on the Finish buttonCheck your score and answers at the end of the quiz, Visit BYJUS for all Chemistry related queries and study materials, Your Mobile number and Email id will not be published. Silver nitrate is a precursor of many other silver compounds that are used. Formula : AgNO3 Synonyms : lunar caustic / nitrate of silver / nitric acid silver salt / nitric acid silver(1+) salt / silver mononitrate / silver nitrate / silver(I) nitrate / silver(I) salt nitric acid . Silver chloride is a white precipitate and nitric acid exists as an aqueous solution. Dentists sometimes use silver nitrate-infused swabs to heal oral ulcers. They are classified as organic and inorganic compounds. Sifat Secara fisik, perak nitrat nampak sebagai padatan putih, tidak berbau dan dalam bentuk kristal. D. emission of light when chemicals are contact with each other. Which of the following is evidence that ionic bonds formed during the precipitation? Common silver objects used in these reactions include silver bullions and silver foils. The halogen atom is displaced as a halide ion: (1) R X + O H R O H + X . v. Ringrose (1981) 4 W.W.R. Its association with argyria made consumers wary and led them to turn away from it when given an alternative. endstream endobj 1824 0 obj <>/Metadata 57 0 R/Outlines 73 0 R/PageLayout/OneColumn/Pages 1821 0 R/StructTreeRoot 186 0 R/Type/Catalog>> endobj 1825 0 obj <>/ExtGState<>/Font<>/XObject<>>>/Rotate 0/StructParents 0/Type/Page>> endobj 1826 0 obj <>stream More information from the unit converter. It is highly soluble in water and also soluble in Ethanol and Acetone. The silver present in the silver nitrate compound is displaced by copper, which forms copper nitrate. Silver nitrate has an orthorhombic crystal structure. Potential Health Effects You should learn about Silver Nitrate | Properties and Structure of Silver Nitrate and Its Applications as it is an essential part of the chemistry syllabus. Colloidal silver is produced when gelatine-containing, aqueous silver solutions absorb ionizing radiation. Molar mass of AgNO3 = 169.8731 g/mol. Treatment of silver nitrate with base gives dark grey silver oxide:[10]. Perak Nitrat: Sifat dan Kegunaan Perak nitrat (AgNO3) adalah senyawa kimia anorganik dan bersifat kaustik yang memiliki berbagai kegunaan yang berbeda. Molecular weight calculation: The Ag-O distances range from 2.384 to 2.702 .[4]. [Cu(NO3)2) [AgNO3 (Cu(NO3)2) [AgNO3)2 O K= This problem has been solved! Causes burns by all exposure routes. However, it is still important to be wary before ingesting any sort of silver-ion solution. skin, mucous membranes, and internal organs. //stream It reflects the change in the way that the halide ion is produced as you go from primary to secondary to tertiary halogenoalkanes. National Center for Biotechnology Information. containing solution is increased. In this video we'll write the correct name for AgNO3. If the formula used in calculating molar mass is the molecular formula, the formula weight computed is the molecular weight. 2. Silver chloride is a white precipitate and nitric acid exists as an aqueous solution.if(typeof ez_ad_units!='undefined'){ez_ad_units.push([[728,90],'chemistryscl_com-medrectangle-3','ezslot_3',110,'0','0'])};__ez_fad_position('div-gpt-ad-chemistryscl_com-medrectangle-3-0'); However, according to the concentration or added amount of hydrochloric acid, there is a possibility to give The molar mass of Silver nitrate is 169.87 gm/mole. This reaction is not a redox reaction because Filter & Sort. As explained earlier, Silver chloride(AgCl) and The products formed in this reaction include silver nitrate, water, and nitrogen oxides. Mass Percent: 63.499%, Element: Nitrogen General Sir James Abbott noted in his journals that in India in 1827 it was infused by a British surgeon into wounds in his arm resulting from the bite of a mad dog to cauterize the wounds and prevent the onset of rabies.[18]. Use of the substance/mixture : Laboratory chemical Chemical intermediate Water treatment These are used to prevent early or premature withering of plants and dropping of buds and flowers. It is a versatile precursor to many other silver compounds, such as those used in photography. In a solid-state, it is 4.35 grams per cubic centimeters. 2 mol AgNO3 ADD FACTOR . % May cause methemoglobinemia, which is characterized by Ingestion: It is still used to determine if moisture on formerly dry cargo is a result of condensation from humid air, or from seawater leaking through the hull. with X is any haligen atom. A student combines a solution of NaCl (aq)NaCl (aq) with a solution of AgNO3 (aq)AgNO3 (aq), and a precipitate forms. Atomic Mass: 14.0067 Silver nitrate is the least expensive salt of silver; it offers several other advantages as well. Silver nitrate is an essential ingredient in colors that are added to ceramic pottery. 1.2. Repeated daily application of silver nitrate can induce adequate destruction of cutaneous warts, but occasionally pigmented scars may develop. Skin: Silver's antimicrobial activity saw many applications prior to the discovery of modern antibiotics, when it fell into near disuse. The branch of chemistry known as analytical chemistry uses this reaction to check for the presence of halide anions such as the iodide, bromide, or chloride ions. This compound is also known as Silver Nitrate. Question: How many milliliters of 0.260 M Na2S are needed to react with 25.00 mL of 0.315 M AgNO3? It is important to note that this reaction must be carried out under a fume hood because of the evolution of poisonous oxides of nitrogen during the chemical reaction. Silver nitrate reacts with these secretions and forms silver chloride. Dilute hydrochloric acid and silver nitrate aqueous solution, With concentrated hydrochloric acid or excess hydrochloric acid, Physical and chemical observation of Pb(NO, Health, safety and environmental impacts due to combustion of ethanol, Ask your chemistry questions and find the answers, Lead nitrate and sodium chloride reaction, What is the limiting reagent and how Please get in touch with us. Symbol: N Silver nitrate is used by some podiatrists to kill cells located in the nail bed. . First, we balance the molecula. It is tempting to think that the reaction will be faster if the electronegativity difference is greater. But, other product nitric acid is a colourless aqueous Investigators use a method called Latent Print development to solve or identify such prints. Cryderman v. Ringrose (1978), 89 D.L.R. Cut stems make ethylene, which helps to hasten the process of fruit ripening and aging of plants. Fisher Scientific Hence care should be taken to store them separately. To tell if AgNO3 (Silver nitrate) is ionic or covalent (also called molecular) we look at the Periodic Table that and see that Ag is a metal and NO3 is a gro. Argyria is a permanent cosmetic condition in which the skin and internal organs turn a blue-gray color. You might, for example, compare the times taken to produce a precipitate from this series of primary halogenoalkanes: Obviously, the time taken for a precipitate of silver halide to appear will depend on how much of everything you use and the temperature at which the reaction is carried out. The silver nitrate reacts with copper to form hairlike crystals of silver metal and a blue solution of copper nitrate: Qualitatively, decomposition is negligible below the melting point, but becomes appreciable around 250C and fully decomposes at 440C.[9]. Colloidal compounds of silver that are used in medicine are also prepared using silver nitrate. //]]>. 2. In its solid state, it has a density of 4.35 grams per cubic centimetre. Ingestion of soluble silver salts may cause argyria, characterized For CHEMTREC assistance, call: 800-424-9300 M = 0.005935 moles H2SO4/50 mL x 100 mL/1L = 0.1187 M H2SO4. Pesticide products that have Silver Nitrate as an active ingredient are used in the cut flower industry. 12H2O solution, and 5 mL of nitrobenzene, (Warning, see ) stopper the flask, and shake vigorously. + NaCl = AgCl + NaNO. The halogenoalkane is warmed with some sodium hydroxide solution in a mixture of ethanol and water. When compared to silver halides, which are used in photography due to their sensitivity to light, AgNO3 is quite stable when exposed to light. However, it is important to be very careful in using this chemical as it can cause damage if improperly handled. Similarly, silver nitrate is used to prepare some silver-based explosives, such as the fulminate, azide, or acetylide, through a precipitation reaction. It is slightly positive because most of the halogens are more electronegative than carbon, and so pull electrons away from the carbon. This compound is also used in medicine owing to its antiseptic qualities. There is a specific reason for this. 1841 0 obj <>/Filter/FlateDecode/ID[<61F264F3603662468A8BF101FC507325><800BD35F28505F47BF9E02A9C1CDFB01>]/Index[1823 33]/Info 1822 0 R/Length 91/Prev 267299/Root 1824 0 R/Size 1856/Type/XRef/W[1 2 1]>>stream This phenomenon is called argyria. Click Start Quiz to begin! 3. If inhaled, this will cause irritation and damage to mucous membranes. Today's world is using digital photography. 0.01 mg/m3 TWA (as Ag) (listed under Silver soluble compounds). Some people have moles on their hands or bodies. The answer is 169.8731. The reason is, that in case of a fire, the Silver Nitrate decomposes, can add to the fire by providing oxygen. So, when this is left exposed to sunlight or any bright light, it will start to hydrolyze. What is the relationship between Ksp and the product of ion concentrations in terms of determining whether a solution if those ions is saturated? [22] Brief exposure will not produce any immediate side effects other than the purple, brown or black stains on the skin, but upon constant exposure to high concentrations, side effects will be noticeable, which include burns. Silver Nitrate when heated decomposes and forms, Silver, Nitrogen dioxide and Oxygen. Causes skin burns. Long-term exposure may cause eye damage. Short-term exposure to this compound does not cause any immediate side effects apart from the development of a violet, brown or black stain on the part of the skin that was in contact with the silver nitrate. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Properties and Structure of Silver Nitrate and Its Applications, The molar mass of Silver nitrate is 169.87 gm/mole. When making photographic film, silver nitrate is treated with halide salts of sodium or potassium to form insoluble silver halide in situ in photographic gelatin, which is then applied to strips of tri-acetate or polyester. The formula weight is simply the weight in atomic mass units of all the atoms in a given formula. Due to the ionic nature of this compound, it readily dissolves in water and dissociates into its constituent ions. 1. << The precipitate thickens up with time. This application will focus on reference electrodes created using a silver wire. When aqueous silver nitrate (AgNO3) Causes eye burns. Mixtures of alkenes can be separated with the help of this compound since the silver cation binds with alkenes in a reversible fashion. Silver nitrate solution can be used to find out which halogen is present in a suspected halogenoalkane. There is no need to make this reaction go to completion. When aqueous silver nitrate (AgNO 3) and aqueous Hydrochloric acid (HCl) are reacted, Silver chloride (AgCl) precipitate and nitric acid (HNO 3) are given as chemical products. Silver Nitrate is a salt, which is colorless or of a white crystalline form. Reverberatory Furnace - History, Construction, Operatio 118 Elements and Their Symbols and Atomic Numbers, Nomenclature of Elements with Atomic Number above 100, Find Best Teacher for Online Tuition on Vedantu. Silver Nitrate is an oxidizing agent, which means it will readily give out oxygen. Its chemical formula is AgNO, . "Silver (metal dust and soluble compounds, as Ag)", National Institute for Occupational Safety and Health, "High Temperature Properties and Decomposition of Inorganic Salts Part 3, Nitrates and Nitrites", "Dr Carl Cred (18191892) and the prevention of ophthalmia neonatorum", "Die Verhrtung der Augenentzndung der Neugeborenen", "Is Creds prophylaxis for ophthalmia neonatorum still valid? Lethal dose for humans is 2 grams, or about 28.6 mg/kg. Silver nitrate can help in fighting gonococcal bacteria in babies and protect them from blindness. Label Each Compound With a Variable. Silver nitrate is developed by reacting silver with nitric acid. Calculate the normality of the AgNO3 solution as Perak nitrat dapat dicirikan oleh beberapa It has been proven that bacteria, Gonococcal Bacteria which is a principal cause of eye infections are eliminated by this chemical. Put your understanding of this concept to test by answering a few MCQs. Fourth Ed. It is also used in the manufacturing of many coloring agents like dyes and inks. It is highly soluble in water and also soluble in Ethanol and Acetone. The Symbol Ag used for Silver originates from the Latin word Argentum. Silver nitrate is soluble in water, with a solubility of 122 grams per 100 milliliters at 0-degree temperature and 256 grams per 100 milliliters at 25-degree temperature. Causes severe irritation of upper respiratory tract with coughing, Contact with other PENDAHULUAN Pada dasarnya kimia analit dibagi mejadi dua yaitu kimia analit kualitatif dan kimia analit kuantitatif. Silver nitrate is broadly used in two fields Medical and industrial applications. 75 (Alta C.A.). and aqueous Hydrochloric acid (HCl) are reacted, AC197680000, AC419350000, AC419350500, AC419352500, AC419360000, 1 Reagent Lane For example: It is more difficult to explain the reason for this, because it needs a fairly intimate knowledge of the mechanisms involved in the reactions. When stuck with light while taking photographs, there would be decomposition to elemental silver, which would leave an image. changed during the reaction process. Sampel di diamkan 5 menit dan dimasukkan . Silver Nitrate is also used in Criminal Investigations. In chemistry, the formula weight is a quantity computed by multiplying the atomic weight (in atomic mass units) of each element in a chemical formula by the number of atoms of that element present in the formula, then adding all of these products together. Atomic Mass: 107.8682 The molar mass of silver nitrate is 169.872 grams per mole. The word "Caustic" means which can corrode. Jaqueline I. Kroschwitz. This is used in the preparation of other silver salts. We use the most common isotopes. The Canadian physician C. A. Douglas Ringrose researched the use of silver nitrate for sterilization procedures, believing that silver nitrate could be used to block and corrode the fallopian tubes. In photographic emulsions, Silver halides are used, and these, in turn, are prepared with Silver nitrate. When this is exposed to light or any organic material, this becomes black in color. Silver nitrate on decomposition gives silver, oxygen gas and nitrite. 0 This could then be developed into a photo by using other chemicals. Silver nitrate is a precursor of many other silver compounds that are used. Thus, the important physical and chemical properties of silver nitrate are briefly described along with its properties. A typical reaction with silver nitrate is to suspend a rod of copper in a solution of silver nitrate and leave it for a few hours. Danger! When aqueous AgNO 3 and aqueous NaCl compounds are mixed together, there is a high chance of giving a white colour precipitate if initial silver nitrate and initial sodium chloride concentrations are considerably high. The formal charge assigned to the nitrogen atom is -1, whereas each oxygen atom holds a charge of -. [24] Argyria is more often associated with the consumption of colloidal silver solutions rather than with silver nitrate, since it is only used at extremely low concentrations to disinfect the water. Designate the volume Vedantu is the best place for you to find these resources. It kills microorganisms and will also react with compounds in human flesh. It can cause vomiting, bloody diarrhea, dizziness and convulsions also. However, if more than 1 gram of silver is accumulated in the body, a condition called argyria may develop. The chemical reaction is represented as given below: In this case, the nitric acid is generally cold and diluted. The Latin word for Moon is Luna, so it was named Lunar Caustic. Strong oxidizer. Silver nitrate does not have any color or odor. C = 49.97g/12g/mol = 4.16 mol. AgNO 3 has a colourless appearance in its solid-state and is odourless. A) The resulting solution is colorless. What is the empirical formula for ethyl fluoride if the compound contains 49.97% carbon, 10.51% hydrogen, and 39.52% fluoride by mass? 22. The weaker the bond, the easier that is. AgNO3 Add 500 ml of water, swirl to dissolve the AgNO3, dilute to the mark with water, and mix. By following the below steps, we can easily balance the equation: First, count the number of each type of atom on both sides. Mass Percent: 8.245%, Element: Oxygen (a) What is the rotational inertia of the cylinder about the axis of rotation? Compare Product No. However, exposure to this compound over long periods of time is often accompanied by damage to the eyes. chocolate-brown colored blood, headache, weakness, dizziness, breath This topic helps you understand the properties, structure, uses, and importance of silver nitrate. The halogen atom is displaced as a halide ion: There is no need to make this reaction go to completion. We have grown leaps and bounds to be the best Online Tuition Website in India with immensely talented Vedantu Master Teachers, from the most reputed institutions. Silver nitrate is a precursor to many compounds of silver, including the silver compounds used in photography. The correct formula written for silver nitrate is AgNO3, or Ag(NO3)2. The alchemists believed that the chemical silver was always associated with the moon. Everything will dissolve in this mixture and so you can get a good reaction. Products Genes Papers Technical Documents Site Content Chromatograms. In the field of dentistry, it is used to heal ulcers in the mouth. For information, call: 201-796-7100 burns, breathing difficulty, and possible coma. %PDF-1.5 % Silver nitrate is a very caustic chemical. Take a quick glance at the revision notes of Silver Nitrate | Properties and Structure of Silver Nitrate and Its Applications before your exam to quickly revise the important points. Fair Lawn, NJ 07410 This page titled Reaction of Alkyl Halides with Silver Nitrate is shared under a CC BY-NC 4.0 license and was authored, remixed, and/or curated by Jim Clark. Thus, this chemical helps in the field of criminal investigations also. [7] In solid silver nitrate, the silver ions are three-coordinated in a trigonal planar arrangement.[4]. Silver Nitrate when heated decomposes and forms, Silver, Nitrogen dioxide and Oxygen. The molar mass of Silver nitrate is 169.87 gm/mole. Description SDS Pricing; 21319-U: pkg of 100 g bulk packing: Expand. Match Criteria: Product Name. This is not the same as molecular mass, which is the mass of a single molecule of well-defined isotopes. You would need to keep the halogen atom constant. Silver nitrate is used to cauterize superficial blood vessels in the nose to help prevent nose bleeds. In addition, it is relatively stable to light, and it dissolves in numerous solvents, including water. Its. El balance REDOX perfecto. hb```,9 [13], In histology, silver nitrate is used for silver staining, for demonstrating reticular fibers, proteins and nucleic acids. Hide. Some of the Chronic effects due to long term exposure to Silver Nitrate are: It can cause general depression, headache, and loss of mental capability. Chronic Chemical Reactions - Description, Concepts, Types, Exam Annealing - Explanation, Types, Simulation and FAQs. However, these days it is not used as a preventive remedy. What is the rusty for deprotection and oxidations. However, this compound tends to decompose at temperatures approaching its boiling point. Various precipitates may be formed from the reaction between the silver and halide ions: It is actually quite difficult to distinguish between these colors, especially if there isn't much precipitate. 2 AgNO3 2 Ag + 2 NO2 + O2. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Na2S (aq) + 2 AgNO3 (aq) 2 NaNO3 (aq) + Ag2S (s) How many milliliters of 0.260 M Na 2 S are needed to react with 25.00 mL of 0.315 M AgNO 3? That is why it has been used in the medical industry. competitive exams, Heartfelt and insightful conversations Ed. Symbol: O (Modern antibiotics are now used instead). Albertus Magnus, in the 13th century, documented the ability of nitric acid to separate gold and silver by dissolving the silver. The chemical equation for this reaction is given by. blood), rapid heart rate, unconsciousness and possible death. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#Y/U~PUH8/?CZ7D|z?O)MuL{!B431 We assume you are converting between grams AgNO3 and mole.You can view more details on each measurement unit: molecular weight of AgNO3 or mol This compound is also known as Silver Nitrate.The SI base unit for amount of substance is the mole. PubChem . Also, hydrochloric acid is a dangerous and corrosive chemical, handle it carefully. Moreover, this chemical compound is an important ingredient of many pesticides that are used in the cut-flower industry. It is common to use bromides because they have moderate reaction rates. AgBr and especially AgI photo-decompose to the metal, as evidence by a grayish color on exposed samples. hWmo6OCDR%y(N N?0%CwDVvlqx/cGO9q P$*TrDTFi+T4)>j>"D'}&}09n+| (s|lTVi(?9&~|]I D C{RlTUZ4TY-1,99((xD[xM!CsB6Nm:u^,6q[y5])O|Zm/F7)K+7m\{ubW DNvXMrXIY4QeqaGp`iV'z_U7run)ml. When diluted with water to a concentration of 0.5%, silver nitrate can serve as an antiseptic in many medical setups. In 1881 Cred introduced the use of dilute solutions of AgNO3 in newborn babies' eyes at birth to prevent contraction of gonorrhea from the mother, which could cause blindness. The chemical equation for the same is shown as: Silver nitrate is a very versatile compound because the nitrate ion can be replaced by other ligands that can bind to the silver ion. and hydrochloric acid reaction. Convert grams AgNO3 to moles. <> It can be observed that silver has an oxidation number of +1 in this compound. The melting point of silver nitrate is 482.8 Kelvin while the boiling point is 713 Kelvin. New York: John Wiley and Sons, 1997. Silver chloride (AgCl) precipitate and nitric acid (HNO3) are given as chemical products. a coordination complex ion, [AgCl2]-. The melting and boiling points of silver nitrate are 482.8 K and 713 K respectively. To learn more about this compound and other silver compounds such as silver chloride, register with BYJUS and download the mobile application on your smartphone. This malady results from According to the above balanced equation, one silver nitrate mol reacts with one hydrochloric acid moles and gives one mol of AC419360250, AC419365000, 19768-0050, 19768-0250, 19768-1000, 19768-5000, It can be used as a stain in scanning electron microscopy.[14]. Kimia analit kualitatif adalah suatu analisa yang bertujuan untuk mengidentifikasi penyusun-penyusun suatu zat, campuran-campuran zat atau larutan-larutan yang biasanya unsur-unsur penyusun zat tersebut bergabung dengan yang satu dengan yang lain, sedang kimia analitit . 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